TPY-6PC type intelligent soil and fertilizer calculation comprehensive tester instructions

Main performance indicators of TPY-6PC intelligent soil and fertilizer calculation comprehensive tester:
First, the measurement project:
(1) Nitrogen, phosphorus, potassium, organic matter in the soil and nitrogen, phosphorus and potassium in the fertilizer can be measured.
(2) Measured pH (pH).
(3) The amount of salt that can be measured (conductance).
Second, nutrient measurement technical indicators:
(1) Stability: A value (absorbance) drifts less than 0.003 within three minutes
(2) Repeatability: A value (absorbance) is less than 0.005
(3) Linearity error: less than 3.0%
(4) Sensitivity: red light ≥ 4.5 × 10 -5 blue light ≥ 3.17 × 10 -3
(5) Wavelength range: red light 620±8nm blue light 440±8nm
(6) Shock resistance: qualified
(Note: The above technical indicators are higher than the national standard)
Third, PH value (pH) measurement technical indicators:
(1) Test range: 1 to 14
(2) Error: ±0.1
Fourth, the amount of salt (conductance) measurement technical indicators:
(1) Test range: 0.01% to 1.00%
(2) Relative error: ± 5%
5. Power supply for this instrument:
(1) AC mains: 180V ~ 240V, 50 Hz (2) DC: 18V, 5W (this instrument comes with)
1. Collection, preparation and storage of soil samples from soil
The collection of soil samples is an important part of determining whether the analysis results correctly reflect soil characteristics. Therefore, it is necessary to choose to collect appropriate soil samples at representative locations. For different analytical purposes, the method of collecting samples is different. Here, only the collection method of mixed samples of cultivated soil is introduced. In order to study the nutrient supply in the tillage layer, it is only necessary to take the soil of about 0-20 cm of the cultivated layer. For the soil with deep roots such as wheat, the sampling depth can be appropriately increased. The sampling point can be determined according to the land area. The smaller area is usually more than 5 points. The larger area (such as 10 mu or more) can be collected more than 20 points. The distribution of sampling points is snake. Shape or diagonal, after mixing, multi-point soil samples are mixed together, and finally about 250 grams is retained as a soil sample for testing.
Second, the test of nutrient content in soil
1. Preparation steps of nitrogen, phosphorus and potassium in the soil to be tested:
(1) Take 2 scoops of soil sample (4 g) into a plastic bottle with a soil sample and add 20 ml of water with a syringe.
(2) Nitrogen and potassium plus 1 tbsp No. 1 powder (about 1 g), cover the bottle cap, shake for 10 minutes, and filter.
(3) Phosphorus plus 1 tbsp No. 2 powder (about 1g), cover the bottle cap, shake for 20 minutes, and filter. Note (If the soil layer to be tested belongs to acidic soil, do not add No. 2 powder, you need to drop 10 drops of No. 3 reagent into the bottle). The filter paper is folded into a funnel shape and inserted into the bottle mouth of the filter bottle, and the shaken soil sample liquid is poured on the filter paper, and the clarified filtrate (test liquid) is obtained in a while.
2. Determination method of ammonium nitrogen in soil:
(1) Take out all the cuvettes.
(2) Blank solution: Add water to the 1st cuvette to a position of two-thirds with a clean plastic pipette as a blank solution and place it in the No. 1 tank.
(3) Standard solution: use a clean plastic pipette to drop 18 drops of water into the 2nd cuvette, then find the “nitrogen standard solution” from the box, add 2 drops of the standard solution, then shake it and place it in the 2nd slot. Medium, as a standard solution for nitrogen. This standard solution concentration is 20 mg/kg (20 ppm).
(4) Solution to be tested: Pipette 20 drops of nitrogen filter into a cuvette No. 3 (No. 4, No. 5, No. 6) with a plastic pipette.
(5) Add 2 drops of No. 1 reagent to the No. 2 and No. 3 (No. 4, No. 5, No. 6) cuvettes, shake well, then add 2 drops of Nitrogen No. 2 reagent and shake well. After parking for 5 minutes, 14 drops of water were added to each and the instrument was used for measurement.
3. Determination method of available phosphorus in soil:
(1) Take out all the cuvettes.
(2) Blank solution: Add water to the 1st cuvette to a position of two-thirds with a clean straw pipette as a blank solution and place it in the No. 1 tank.
(3) Standard solution: use a clean straw to drop 18 drops of water into the 2nd cuvette, then find the “phosphorus standard solution” from the box, add 2 drops of the standard solution, and shake it to meet the standard of phosphorus. liquid. This standard solution concentration is 20 mg/kg (20 ppm).
(4) To be tested: Draw 16 drops of water with a straw pipette and 4 drops of phosphorus filter into the cuvette No. 3 (No. 4, No. 5, No. 6) and shake well.
(5) Add 2 drops of Phosphorus No. 1 reagent to the No. 2 and No. 3 (No. 4, No. 5, No. 6) cuvettes, shake well, add 1 drop of Phosphorus No. 2 reagent, and then add 14 drops of water. Shake well and measure on the instrument.
4. Method for determination of available potassium in soil
(1) Take out all the cuvettes.
(2) Blank solution: Add water to the 1st cuvette to a position of two-thirds with a clean plastic pipette as a blank solution and place it in the No. 1 tank.
(3) Standard solution: use a clean plastic pipette to drop 18 drops of water into the No. 2 cuvette, then find the “potassium standard solution” from the box, add 2 drops of the standard solution, and shake well to serve as the standard solution for potassium. . This standard solution concentration is 100 mg/kg (100 ppm).
(4) Test solution: Pipette 20 drops of potassium filter into a cuvette No. 3 (No. 4, No. 5, No. 6) with a plastic pipette.
(5) Add 2 drops of Potassium No. 1 reagent to the No. 2 and No. 3 (No. 4, No. 5, No. 6) cuvettes, shake well, and then add 2 drops of Potassium No. 2 reagent and shake well. After parking for 5 minutes, 14 drops of water were added to each and the instrument was used for measurement.
5 , the method of organic matter in the soil:
The phosphorus leaching filtrate is poured into a small test tube for a small amount, and the organic matter content of the soil sample can be obtained by comparison with the color card.
6. Determination of salt in soil
(1) Determination of significance:
As an important land resource, the area of ​​saline soil in the world is 954.3 million hectares. The total area of ​​saline soil in China is 99.13 million hectares. In the cultivated land of the agricultural area, not less than 100 million mu of saline soil is still the main reason for the large and medium-sized low-yield. Therefore, the rational use of the potential to improve and develop saline land resources is of paramount importance in the sustainable development of the national economy.
(2) Method for determining soil salinity
A. Preparation of the test solution: Weigh 10.0 g of air-dried soil sample through a 2 mm sieve hole into a 100 ml triangular flask, add 50 ml of carbon dioxide-free water, and shake for 3 minutes on a shaker (or vigorously by hand). Filtration is the liquid to be tested.
B. Preparation of standard mother liquor:
Soil type
Na 2 SO 4 (g)
NaCL(g)
NaHCO 3 (g)
Constant volume (ml)
concentration(%)
Sulphate soil
15.163
1.249
3.588
1000
2.0
Chloride soil
1.723
14.199
4.078
1000
2.0
Bicarbonate soil
2.584
2.130
15.286
1000
2.0
C, standard working fluid preparation:
1 0.5% standard working solution preparation: Pipette 25ml of the standard mother liquor in the above table into a 100ml volumetric flask and dilute it with distilled water.
2 0.05% standard working solution preparation: Pipette 2.5ml of the standard mother liquid in the above table into a 100ml volumetric flask and dilute to volume with distilled water. (3) On-board instrument measurement: Please refer to the instrument screen display Chinese character prompt.
7. Determination of pH in soil
(1) Determination of significance:
Soil pH is one of the important basic properties of soil, and it is an indicator of soil formation and ripening and fertilization process. In the soil, it participates in many chemical reactions that affect many soil properties. Microbial activity, synthesis and decomposition of organic matter, soil nutrient retention, and migration of elements during soil development are all related to soil pH. Various plants have a suitable pH range beyond which growth is hindered. Therefore, the significance of soil pH determination is not limited to understanding the pH of the soil itself, but many other soil properties can be judged or extrapolated based on the pH.
(2) Classification of soil pH grade In soil science, according to the law of soil zonal distribution in China, it is more suitable to divide the pH of soil into five grades in practical application. Strong acidity (pH < 5.0), acidity (pH 5.0 to 6.5), neutral (pH 6.5 to 7.5), basic (pH 7.5 to 8.5), and strong alkaline (pH > 8.5).
(3) Method for determining the pH of soil (Method 1) Visual colorimetry:
Take 3 flat spoons of soil into the soil sample bottle, add tap water to the mark line (20ml), shake for 5 minutes, then filter, take 20 drops of the filtrate into the glass test tube with a plastic pipette, and add 2 drops of PH reagent to the test tube. After shaking, observe the color with the eye and compare it with the color chart in the manual. If the measured result is green, both dark green and light green are neutral, pink is acidic, and blue is alkaline.
(Method 2) Electrode method:
(1) Preparation of standard solution 1PH4.01 standard buffer: The reagent of pH 4.01 was dissolved in distilled water without carbon dioxide, and the volume was adjusted to 250 ml of the volumetric flask to be the pH 4.01 standard buffer.
2PH9.18 standard buffer: The reagent of PH9.18 was dissolved in distilled water without carbon dioxide, and the volume was adjusted to 250 ml of the volumetric flask to be the pH 9.18 standard buffer.
(2) Preparation of soil pH value test solution Weigh 10 g of air-dried soil sample through a 2 mm sieve hole in a soil sample bottle, add 50 ml of carbon dioxide-free distilled water, vigorously stir or shake with a glass rod for 1-2 minutes, Set for 30 minutes and then measure with the instrument.
(3) Measurement method steps: For the instrument measurement method steps, please see the instrument screen display Chinese characters prompt.
Instrument operation flow and screen display

Press the SELECT or ENTER button
nutrient
Amount of salt
PH value
Test nutrient operation process and screen display diagram:

Press the SELECT or ENTER button
Nitrogen organic matter
phosphorus
Potassium
Please aim at the blank
T=××××
Press the confirmation button after stabilization
Press the SELECT button, the arrow can be pressed to press the SELECT button, the arrow can be cycled
Ring move, to the required test, move to the required test item and press
Press the confirmation key after the item

Preset standard solution [ppm]
20 50 80 125
40 60 100 200
Press the SELECT or ENTER button
Please align the standard solution
A=××××
Press the confirmation button after stabilization
key

Press the ENTER button to stabilize and press the ENTER button.

Print...press the print button
Reset... press the enter key
Please align the measured liquid No. 1
□=××××
Press the SELECT or ENTER button
(Note: Nitrogen is N and phosphorus in "â–¡"
Press the SELECT button, the arrow can be followed by P, organic matter C)
Move the ring to the required standard liquid to measure the next measured liquid, such as straight
Press the confirmation button after the density value, press the print button.
2 , test the salt volume operation process and screen display diagram:

Probe inserted 0.50 standard solution
Concentration: ××××%
Press the confirmation button after stabilization
 

Probe inserted 0.05 standard solution
Concentration: ××××%
Press the confirmation button after stabilization
Press the selection button, the arrow can follow
Ring movement, to salt test
Press the confirmation button after the item. Press the enter key.

Print...press the print button
Reset... press the enter key
Probe inserted into the test solution 1
Concentration = × × × × %
Press the SELECT or ENTER button
Press the SELECT button to measure a test solution.
Press the Enter key. If you print directly, press the Print button.

3. Test the PH value (pH) operation flow and screen display diagram:

Probe inserted 9.18 standard solution
PH: ×××
Press the confirmation button after stabilization
Probe inserted 4.00 standard solution
PH: ×××
Press the confirmation button after stabilization
 
Press the selection button, the arrow can follow
Ring movement, to PH value
Press the confirmation button after the test item, press the enter key.

Print...press the print button
Reset... press the enter key
Probe inserted into the test solution 1
PH: ×××
Press the SELECT or ENTER button
Press the SELECT button to measure a test solution.
Press the Enter key. If you print directly, press the Print button.
Basic configuration 1. Main functions:
Manage operators, set permissions, and configure port numbers for communication.
Second, the method of operation
1. User rights management (1) Only the system administrator is allowed to add, modify, delete and password initialize the user.
(2) The system administrator currently logged in cannot delete itself.
(3) The current system administrator who logs in can modify other users, and can only modify the user name, real name and permissions, and cannot change the password.
(4) The currently logged-in system administrator can perform password initialization for the user who forgot the login password, and restore the user password to 12345678.
(5) The currently logged-in system administrator, when adding a user, only enter the user name and real name, the password is automatically initialized to 12345678.
(6) The current user who logs in can only modify his own information, but does not have the right to view the user list, nor can he change his own permissions.
Note: Please fill in the real name correctly and this name will be used for the test report.
2, port number setting The first step, if the machine does not have a serial port, please first properly install the included USB installation disk, virtual one serial port on the machine.
The second step is to check the serial port number that the unit can communicate with. (View in "Device Manager/Port (COM and LPT)" of this machine)
In the third step, after selecting the radio button corresponding to the serial port number to be communicated, click the OK button to complete the port setting.
Data backup and recovery
First, the main function:
Back up your data and restore if necessary. The data mainly includes various parameter settings and test report records.
Second, the operation method The first step, choose whether you need to backup or need to recover.
In the second step, click the Start button to complete this function.
Sample registration page use
First, the main function Complete the registration of the sample to be tested. Subsequent test/analysis/query operations can only be performed on registered samples.
Second, the method of operation
(1) The “sample number” and “send inspection unit” on this page are required, and the rest are optional.
(2) After the registration of a sample is completed, press the “OK” button to save. Note that the “sample number” is used as a sample and cannot be repeated.
(3) For the samples listed in the “Untested Sample List”, if it is out of date due to expiration or other reasons, you can click the “Delete” button to delete.
(4) It can be registered multiple times in succession. After all registrations are completed, you can press the “Exit” button to close this interface and perform subsequent operations.
Sample test
First, the basic function From the list of untested samples registered, select samples for testing, and the results will be used for subsequent data analysis.
Second, the operation steps The first step: select the sample of this test from the list of samples to be tested.
Select the sample to be tested in the sample to be tested. A check mark appears before the selected sample number. Click the “Add” button after the selection is finished. The selected sample number appears in the test selection bar below. At the same time, in the sample list to be tested, the selected sample record will be deleted.
It can be added multiple times, but in one test, up to 8 samples can be measured simultaneously.
If you are not satisfied with the selected sample, you can click the “Reselect” button to perform the reselection.
Step 2: Receive test data Click the “Test” button, and the computer is in the state of receiving data sent by the tester, and the received data is automatically filled.
At this point, the button of the button changes to "stop".
There is no time interval requirement between the two sets of data. If one group of measurement data is not satisfied, the measurement can be repeated, and the computer will automatically overwrite the original data of the group with the new measurement data.
During the receiving data phase, no other operations will be possible.
Step 3: Terminate the receiving data Click the “Stop” button to terminate the receiving data, and the button label will return to “Test”. In this case, if the data is found to be in doubt, the data in question can be re-tested. In this case, just click the “Test” button again and it will be in the receiving state.
Step 4: Save the test results Before clicking the “Save” button, if “Temporary Save” is checked, the save operation is temporarily saved, otherwise it is saved. The difference between temporary storage and final preservation is that temporarily saved data cannot be analyzed.
Step 5: Analyze the test results If the test results are final saved, you can select the same in the test sample column and click the “Analyze” button to analyze the sample.
After analyzing one sample, you can continue to analyze other samples.
Step 6: Click the “Next Group” button to start the process of adding, testing, saving, and analyzing a new set of samples.
Result analysis
First, the main function The results of the selected sample test are analyzed.
Second, the operation method (A) set the system parameters as needed.
(2) Select “Planted Crops” and “Target Yield”, click the “OK” button on the left to complete the analysis of the amount of fertilizer, pH and salt.
(3) Fill in the parameters of the fertilizer to be used, and click the “Analyze” button at the bottom to complete the analysis of the optimal demand for the fertilizer.
For the same sample, different analyses can be performed multiple times, such as different crops, different yields, and different fertilizers are analyzed multiple times in order to obtain the best benefit, but each test is followed by “OK”. Button, then press the "Analyze" button in the order.
(4) Carry out the necessary fertilization instructions for the best demand results produced by the analysis.
(5) After the analysis results are satisfactory, click the “Save” button to save.
(6) This result can be printed by clicking the "Print" button. Before using this feature, make sure your computer is properly connected to the printer.
(7) This result can be sent directly to the customer-designated mailbox by clicking the “Send Mail” button. This feature calls Outlook that comes with the Windows system. Before using this feature, please configure it correctly first. Once properly configured, this feature is available when the computer is online.
Query 1. Main function Complete the inquiry function based on the condition of the inspection unit.
Second, the operation method (1) Select the specific unit or all in the list of inspection units, click the "Query" button to perform the query operation.
(2) After selecting a specific sample in the sample list, click on the display to enter the analysis interface and display/analyze the sample.
(3) If some samples in the sample list have no reserved value, click the Delete button to delete.
Outlook settings (take 163 as an example. For other specific configuration methods, please consult the corresponding service provider of the mail system used)
First, Outlook Express settings are as follows:
1. Click on "Accounts" in the "Tools" menu.
2. Click "Add" and select "Mail" in the pop-up menu to enter the Internet Connection Wizard.
3. Enter your "display name" and click "Next".
4. Enter your email address and click "Next".
5. Enter the POP3 and SMTP server address of your mailbox and click "Next".
6. Enter your account name (only the part before @) and password.
7. Click the "Finish" button to save your settings.
8. In the Internet account, select the "Mail" tab, select the account you just set, and click "Properties".
9. In the Attribute Settings window, select the "Server" tab, check "My server requires authentication" and click the "Settings" button next to it.
10. Login information Select "Use the same settings as the receiving mail server", click "OK" to return.
(The specific steps are as follows:)
Second, Microsoft Outlook settings are as follows:
1. Click on "Account" in the "Tools" menu.
2. Click "Add" and select "Mail" in the pop-up menu to enter the Internet Connection Wizard.
3. Enter your "display name" and click "Next".
4. Enter your email address and click "Next".
5. Enter the POP3 and SMTP server address of your mailbox and click "Next".
6. Enter your account name (only the part before @) and password, click "Next".
7. Choose how to connect to the Internet.
8. Click the "Finish" button to save your settings.
9. In the Internet account, select the "Mail" tab, select the account you just set, and click "Properties".
10. In the Attribute Settings window, select the "Server" tab, check "My server requires authentication" and click the "Settings" button next to it.
11. Login information Select "Use the same settings as the receiving mail server", click "OK" to return.
(The specific steps are as follows:)
Soil organic matter colorimetry
  (Hydration heat-oxidation reaction method)
(1) Determination steps:
1: Pipette 3.0 ml of distilled water into a clean beaker and use as a blank.
2: Weigh 1 g of air-dried soil sample (accurate to 0.001 g) through a 0.5 mm aperture into another clean beaker, and then add 3 ml of distilled water to fully shake the soil sample.
3: Pipette 2 ml of soil organic matter standard solution into another clean small beaker and add 1 ml of distilled water to a content of 10 mg.
4: Add 10 ml of potassium dichromate solution and 10 ml of concentrated sulfuric acid to each of the above small beakers, shake continuously, park for 20 minutes, then add 10 ml of distilled water, shake well, and then settle the sediment (Note: Conditional The user can centrifuge the mixture in a small beaker with soil samples.
5: Pipette each solution in the above small beakers (small beakers with soil samples to be clarified) to 10 ml each, put them into a 50 ml volumetric flask, dilute to the mark with distilled water, and shake well.
6: Colorimetric determination of the instrument: For details, please refer to the method of using the instrument in the instruction manual.
(2) Calculation of results:
Soil organic matter content is expressed as a percentage, retaining two decimal places.
Soil organic matter (%) = [(C × 1.724) / (m × 10 )] × 100 × 1.32
=(C/m)×0.23
Where: C——the content of the liquid to be tested m——the quality of the soil (1 g)
Reagent preparation method:
Concentrated sulfuric acid: 98% (analytical grade)
Potassium dichromate solution: Weigh 39.23 g of potassium dichromate (analytical grade), dissolve it in 600 ml of water, dissolve it, and dilute to 1 liter with distilled water.
0.5%-C standard solution: Weigh 1.376 g of glucose (chemically pure) in a 100 ml volumetric flask, add distilled water to dissolve, add 1 ml of concentrated sulfuric acid, add water to volume, shake well, the standard solution contains 5 mg of carbon. /ml.
TPY-6PC instrument packing list
1, TPY-6PC type instrument host 1
2, reagent packaging box and reagents 1 set
3, pH composite electrode 1
4, salt conductivity electrode 1
5, instrument power cord 1
6, the data line 1
7. Color chart 1
8, product warranty card certificate 1
9, the manual 1
Note: In the second time you purchased the reagent separately, do not contain acid buffer powder, please go to the local reagent store to buy

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